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袁斌芳博士


来源:本站原创 作者:佚名 日期:2019-05-29 访问次数:4570


袁斌芳,男,中共党员,副教授,理学博士,现任化学化工学院教师。

本人长期从事化学反应机理的研究工作,具体研究内容包括以下三个方面:有机小分子酸碱对有机催化反应影响的机理探究;基于绿色有机化学合成固化CO2气体的机理探究;自燃配合物的设计及其对燃烧反应促进机制的探究。先后主持了2016年第三批中央高校基本业务费专项博士项目1项,重庆市教委项目1项,长江师范学院高层次人才科研启动项目1项,长江师范学院青年科研人才成长支持计划1项;作为项目主研人参与重庆市科委自然科学基金3项,重庆市教委项目1项;在Organic Letters》、《Nanomaterials》、《Physical Chemistry Chemical Physics Chemisty》、《Journal of Organic Chemistry》、《Asian Journal of Organic Chemistry》、《European Journal of Organic Chemistry》、《New Journal of Chemistry》、《Applied Organometallic Chemistry国内外刊物上发表学术论文37篇。

承担本科生《化学信息学》、《有机化学》、《有机化学实验》、《无机及分析化学实验》等课程。

 

联系邮箱6781022@163.com

 

学习及工作经历

2010.09-2013.06,西南大学,化学化工学院,物理化学硕士;

2014.09-2017.06,西南大学,化学化工学院,物理化学博士;

2013.06-2013.10,山东现代学院,护理学院,专业教师;

2013.10-2014.09,中科院苏州纳米技术与纳米仿生研究所,研究员助理;

2017.06-至今,   长江师范学院,化学化工学院,专业教师。

 

主持的主要科研项目(近5年)

1. 重庆市教委项目,质子shuttle对一类金属催化有机反应机理影响的理论研究,主持,2019.01~2021.12

2. 重庆市教委项目,基于二硫化钼量子点构建生物小分子的无创性监测平台,主研,2019.01~2021.12

3. 长江师范学院青年科研人才成长支持计划,配体及有机小分子添加剂对有机催化反应中质子转移机理的影响,主持,2018.01~2022.12

4.长江师范学院引进人才科研启动项目,添加剂与配体对有机催化反应机理的影响,主持,2018.01~2022.12

5. 重庆市科委项目,磺酰化新反应的开发及其在含砜药物合成中的应用研究,主研,2018.01~2020.12

6. 重庆市科委项目,铯催化杂取代烯烃的不对称合成及其在药物分子合成中的应用研究,主研,2018.01~2020.12

7.重庆市科委项目,密度泛函理论研究表面等离基元共振在光催化CO2还原中的应用,主研,2016.01~2018.12

8. 2016年第三批中央高校基本业务费专项学生项目,配体和添加剂作为质子shuttle对催化反应的影响,主持,2016.04-2016.12

 

代表性论文(第一作者或通讯作者,近5年):

第一作者

1. Binfang Yuan*, Huimin Zhou, Youqing Yu, Xiaogang Guo, Yu Zhao, Fulan Zhang, Haimei Zhou, Huisheng Huang* and Rongxing He*. DFT study on the [4+4] domino cycloaddition of ynones with benzylidenepyrazolones to access eight-membered cyclic ethers: effects of DBU vs. Et3N. New Journal of Chemistry,2021, 45: 131-140.

2. Binfang Yuan, Jingwei Wan, Xiaogang Guo, Yongmi Gong, Fulan Zhang, Qing Li, Guangzhao Wang*, Jinyang Chen*, Rongxing He*. Theoretical investigation on the Cu(I)-catalyzed N-carboxamidation of indoles with isocyanates to form indole-1-carboxamides: effects of solvents. New Journal of Chemistry,2020, 44: 9876-9887.

3. Binfang Yuan, Jinyang Chen, Guangzhao Wang, Fulan Zhang, Luqiu Fang, Xiaogang Guo*, Huisheng Huang*, Rongxing He*. DFT Study on the Gold(I)-catalyzed dehydrogenative heterocyclization of 2-(1-alkynyl)-2-alken-1-ones to form 2,3-furan-fused carbocycles: effects of additives C5H5NO vs. PhNO. Applied Organometallic Chemistry, 2020, 34: e5443.

4. Binfang Yuan, Zhenjie Tang, Yinhe Lin, Guangzhao Wang, Luqiu Fang, Xiaogang Guo, Youli Zhao, Xiaohua Xie*, Jinyang Chen*, Rongxing He*. Insights into the mechanisms of Cu(I)-catalyzed heterocyclization of alpha-acyl-alpha-alkynyl ketene dithioacetals to form 3-cyanofurans: the roles of NH4OAc. New Journal of Chemistry,2019, 43: 19149-19158.

5. Binfang Yuan, Jinyang Chen, Xiaohua Xie, Shuhua He, Yafei Luo, Xiaogang Guo*, Huisheng Huang*, Rongxing He*. Insights into the mechanisms of Ag-catalyzed synthesis of CF3-substituted heterocycles via [3+2]-cycloaddition from trifluoromethylated methyl isocyanides: effects of DBU and exploration of diastereoselectivity. New Journal of Chemistry,2019, 43: 9265-9273.

6. Binfang Yuan, Xiaogang Guo, Guangzhao Wang, Huisheng Huang, Fulan Zhang, Jianhua Xu*, Rongxing He*. Theoretical investigation on the mechanism of Cu(II)-catalyzed synthesis of 4-quinolones: effects of additives HOTf vs. HOTs. New Journal of Chemistry,2019, 43: 4291-4305.

7. Binfang Yuan, Rongxing He, Xiaogang Guo, Fengying Zhang, Yanyan Xu, Ming Li*. DFT study on the Au(I)-catalyzed cyclization of indole-allenoate: counterion and solvent effects. New Journal of Chemistry, 2018, 42: 15618-15628.

8. Binfang Yuan, Rongxing He, Wei Shen, Ming Li*. Effects of base strength on the copper-catalyzed cycloisomerization of propargylic acetates to form indolizines: A DFT study. Tetrahedron, 2017, 73(42): 6092-6100.

9. Binfang Yuan, Rongxing He, Wei Shen, Ming Li*. Influence of base strength on the proton-transfer reaction by density functional theory.European Journal of Organic Chemistry, 2017, (25): 3947-3956.

10. Binfang Yuan, Rongxing He, Wei Shen, Yanyan Xu, Xiaorui Liu, Ming Li*. Theoretical investigation on mechanism of the PPh3-catalyzed isomerization of allenic sulfones to 2-arylsulfonyl 1,3-dienes: effects of additive as the proton-shuttle. ChemistrySelect, 2016, 1(11): 2971-2978.

11. Binfang Yuan, Rongxing He, Wei Shen, Weixia Hu, Ming Li*. DFT study on the CuBr-catalyzed synthesis of highly substituted furans: effects of solvent DMF, substrate MeOH, trace H2O and the metallic valence state of Cu. RSC Advances, 2016, 6(24): 20294-20305.

12. Binfang Yuan, Rongxing He, Wei Shen, Cheng Huang, Ming Li*. Mechanistic insights into the Cu(I)- and Cu(II)-catalyzed cyclization of o-Alkynylbenzaldehydes: the solvent DMF and oxidation state of copper affect the reaction mechanism. Journal of Organic Chemistry,2015, 80(13): 6553-6563.

通讯作者

1 Quan Gou*, Binfang Yuan*, Man Ran, Jian Ren, Ming-zhong Zhang, Xiaoping Tan, Tengrui Yuan, Xing Zhang. C(sp3)-H monoarylation of methanol enabled by a bidentate auxiliary. Organic Letters, 2021, 23(1): 118-123.

2. Yibin Zhang, Binfang Yuan*, Dongge Ma*. Selective recognition of Zn(II) ions in live cells based on chelation enhanced near-infrared fluorescent probe. Inorganica Chimica Acta, 2020, 508: 119640.

3. Jinyang Chen, Rui Chen, Lan Mei, Shanshu Yan, Yan Wu, Qiang Li, Binfang Yuan*. Visible-light-induced difunctionalization of styrenes: an efficient and green protocol for the synthesis of β-acyloxyselenides. Asian Journal of Organic Chemistry, 2020, 9: 181-184.

4. Guangzhao Wang*, Linxi Gong, Zongfeng Li, Biao Wang, Wanli Zhang, Binfang Yuan, Tingwei Zhou, Xiaojiang Long, Anlong Kuang. Two-dimensional CdO/CdS heterostructure used for visible light photocatalysis. Physical Chemistry Chemical Physics Chemisty, 2020, 17: 9587-9592.

5. Jinyang Chen, Lan Mei, Jialing Liu, Chuntao Zhong, Binfang Yuan*, Qiang Li. Microwave-assisted iodine-catalyzed oxidative coupling of dibenzyl(difurfuryl)disulfides with amines: a rapid and efficient protocol for thioamides. RSC Advance, 2019, 9: 28576-28580.

6. Jinyang Chen*, Li Hu, Haiying Wang, Lingrong Liu, Binfang Yuan*. Copper(I)-catalyzed N-carboxamidation of indoles with isocyanates: facile and general method for the synthesis of indole-1-carboxamides. European Journal of Organic Chemistry, 2019, 3949-3954.

7. Guangzhao Wang, Feng Zhou, Binfang Yuan*, Shuyuan Xiao, Anlong Kuang, Mingmin Zhong, Suihu Dang, Xiaojiang Long, Wanli Zhang. Strain-tunable visible-light-responsive photocatalytic properties of two-dimensional CdS/g-C3N4: A hybrid density functional study. Nanomaterials2019, 9: 244.


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